Starbucks - EWR Airport, Terminal B is open 24 Hours.
Newark Liberty International Airport is currently the only airport in United States that proudly opens its doors 24 Hours a day.
I had a 10 hour layover in New Jersey for my international flight and I spent some time at this Starbucks. Plenty of seating including large food court selection next to this Starbucks.
It does get fairly busy 03:00-21:00, as it's in a high foot traffic area. It's located one floor below International Airlines Ticket Counters and Security Check Point.
"PLEASE NOTE: A 3% employee benefits & retention surcharge has been applied to your purchase. This surcharge is not a gratuity payable directly to staff."
Overall I would say it's a good atmosphere and safe. Staff was ok, not great. But it wouldn't be fair to judge them since they're working in middle of the night.
Police patrol this area frequently throughout the night.
Cautionary Statement: They do have homeless people that are polite, but will come up to you and ask you to buy them something at this Starbucks location. I had several come up to me. (Not really used to that at an airport)
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