Having visited Pompeii in the past, I was always wanting to dive the "underwater version" - the…read moreCentro Sub Campi Flegrei is a very short boat ride from the archeological site. Their dive masters are VERY familiar with all of the artefacts and the layout of the underwater city ruins.
They were extremely helpful (they have English-fluent staff) and accommodating for divers of all levels. They also offer snorkeling for non-certified. As a dive-shop, they also offer PADI certification classes (though I did not use them for this).
The 2 or 3 different dives they off are beginner level dives. All of their staff were very helpful - for the Americans, remember that you're not in the USA and get used to living the more relaxed Italian lifestyle!